Here is the list of license cards you can unlock in Marvel vs. Capcom 3: Fate of Two Worlds for the PS3 and Xbox 360.
1st License Card – Complete Arcade Mode with a character on any difficulty
2nd License Card – Complete Arcade Mode with a character on Very Hard
3rd License Card – Complete five Missions with a character
4th License Card – Complete all missions with a character
5th License Card – Use any character 30 times